Preheat your oven to 350°F (175°C).
Coat two 9-inch round cake pans with a thin layer of oil or butter, then dust them with a bit of flour to help prevent sticking. You may also line the bottoms with parchment and grease that too.
In a bowl, sift the cake flour, baking powder, and a pinch of salt together to ensure they are well combined and to add lightness to the mixture.
In another bowl, whisk together the buttermilk and egg whites until well blended.
In a mixing bowl, rub the lemon zest into the sugar using your fingers until fragrant.
Mix the softened butter with the sugar and whip them together on medium speed for about five minutes, until the texture becomes smooth and airy.
Blend in the vanilla extract.
Gradually incorporate the dry ingredients in three parts, alternating with the milk-egg mixture. Begin and end with the dry mix.
Beat the batter for an extra 1–3 minutes to ensure it’s fully combined and smooth.
Divide the batter evenly into your prepared pans.
Bake the cakes for 30 to 40 minutes, or until a toothpick poked into the middle comes out without any wet batter.
Let cakes cool in the pans for 5 minutes, then turn out onto wire racks. Remove parchment if used and let them cool completely.